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Electrophilic Displacement Reactions. XVI. Metal Ion Catalysis in the Protodeboronation of Areneboronic Acids 1-3

✍ Scribed by Kuivila, Henry G.; Reuwer, Joseph F.; Mangravite, John A.

Book ID: 121420137
Publisher: American Chemical Society
Year: 1964
Tongue: English
Weight: 575 KB
Volume: 86
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01067a031

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Electrophilic Displacement Reactions. X. General Acid Catalysis in the Protodeboronation of Areneboronic Acids 1-3

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Electrophilic Displacement Reactions. XI

Electrophilic Displacement Reactions. XII. Substituent Effects in the Protodeboronation of Areneboronic Acids 1-3

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Electrophilic Displacement Reactions. XI

Electrophilic Displacement Reactions. XI. Solvent Isotope Effects in the Protodeboronation of Areneboronic Acids 1-3

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Electrophilic Displacement Reactions. VI

Electrophilic Displacement Reactions. VII. Catalysis by Chelating Agents in the Reaction between Hydrogen Peroxide and Benzeneboronic Acid 1,2,3

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Electrophilic Displacement Reactions. IV

Electrophilic Displacement Reactions. IV. Kinetics of the Brominolysis of m-Chlorobenzeneboronic Acid in Aqueous Solution 1-3

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Alkali-Metal-Ion Catalysis and Inhibitio

Alkali-Metal-Ion Catalysis and Inhibition in the Nucleophilic Displacement Reaction of Y-Substituted Phenyl Diphenylphosphinates and Diphenylphosphinothioates with Alkali-Metal Ethoxides: Effect of Changing the Electrophilic Center from PO to PS

✍ Prof. Ik-Hwan Um; Young-Hee Shin; Jee-Eun Park; Ji-Sun Kang; Prof. Erwin Buncel 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 398 KB 👁 2 views

## Abstract A kinetic study of the nucleophilic substitution reaction of Y‐substituted phenyl diphenylphosphinothioates **2 a**–**g** with alkali‐metal ethoxides (MOEt; M=Li, Na, K) in anhydrous ethanol at (25.0±0.1) °C is reported. Plots of pseudo‐first‐order rate constants (__k__~obsd~) versus [M