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The Participation of Heavy Metal Ions in the Hydrolysis of Amino Acid Esters 1

โœ Scribed by Kroll, Harry

Book ID
126757782
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
469 KB
Volume
74
Category
Article
ISSN
0002-7863

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Metal Ion Catalysis in the Hydrolysis of
Metal Ion Catalysis in the Hydrolysis of Esters of 2-Hydroxy-1,10-phenanthroline: The Effects of Metal Ions on Intramolecular Carboxyl Group Participation
โœ Thomas H. Fife; M.P. Pujari ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 207 KB

Rate constants have been determined for hydrolysis of the acetate, glutarate, and phthalate monoesters of 2-hydroxy-1,10-phenanthroline in water at 30 degrees C and &mgr = 0.1 M with KCl. The hydrolysis reactions of the esters are hydroxide ion catalyzed at pH > 9. The phthalate and glutarate monoes