Multiple metal ion participation in cobalt(III) promoted hydrolysis of orthophosphate esters

Metal Ion Catalysis in the Hydrolysis of

Metal Ion Catalysis in the Hydrolysis of Esters of 2-Hydroxy-1,10-phenanthroline: The Effects of Metal Ions on Intramolecular Carboxyl Group Participation

✍ Thomas H. Fife; M.P. Pujari 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 207 KB

Rate constants have been determined for hydrolysis of the acetate, glutarate, and phthalate monoesters of 2-hydroxy-1,10-phenanthroline in water at 30 degrees C and &mgr = 0.1 M with KCl. The hydrolysis reactions of the esters are hydroxide ion catalyzed at pH > 9. The phthalate and glutarate monoes