The reactions between F2 and the lowest members of the homologous series of perfluoroalkyl iodides (CF31. C2F51. and n-C3F71) have been studied. For these compounds, an exponential decrease in the alkyl iodide concentration over time following an induction period is observed for certain experimental
The collisionless IR absorption spectrum of C3F7I
β Scribed by P. Mukherjee; H.S. Kwok
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 400 KB
- Volume
- 125
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The collisionless infrared absorption spectrum of C,F,I was measured with an 80 ns CO* laser system. Comparison with the collisional absorption spectrum reveals that collisions induce a red-shift as well as significant broadening of the collisionless spectrum. The collisional broadening contribution was found to be much larger than anticipated. Possible physical explanations are given.
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