The Chlorination of Aliphatic Amines 1
β Scribed by Amundsen, Lawrence H.; Pitts, Leonard S.
- Book ID
- 126064119
- Publisher
- American Chemical Society
- Year
- 1951
- Tongue
- English
- Weight
- 572 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The oxidation of aliphatic amines by aqueous chlorine has been studied. The kinetic behaviour is similar for primary, secondary and tertiary aliphatic amines, the elementary step being the transfer of chlorine from the hypochlorous acid molecule to the nitrogen of the f~e amino group. Chlorination o
Oxidation of Aliphatic Amines by Aqueous Chlorine. -A mechanistic study is done. The elementary step is the transfer of chlorine from the hypochlorous acid molecule to the nitrogen of the amino group. For primary and secondary amines H 2 O molecules are involved in the transition states.