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The chiral amino alcohol, cis-2-amino-1-acenaphthenol: Synthesis, resolution, and application to the diastereoselective [2,3]-Wittig rearrangement

✍ Scribed by Atsushi Sudo; Yukihiko Hashimoto; Hiroki Kimoto; Kazuhiro Hayashi; Kazuhiko Saigo

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 905 KB
Volume: 5
Category: Article
ISSN: 0957-4166
DOI: 10.1016/0957-4166(94)80175-4

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✦ Synopsis

The cbiral amino alcohol, cis-Zamino-1-acenaphthenol, was synthesized, and resolved by a simple procedure. This new chiral amino alcohol was converted into an oxaxoline derivative and applied as a chiral auxiliary to the diastereoselective (2.3]-Wittig rearrangement.

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