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The Chemistry of Vicinal Tricarbonyls and Related Systems

โœ Scribed by Wasserman, Harry H.; Parr, Jonathan

Book ID
120250733
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
444 KB
Volume
37
Category
Article
ISSN
0001-4842

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๐Ÿ“œ SIMILAR VOLUMES

The chemistry of vicinal tricarbonyls. F
The chemistry of vicinal tricarbonyls. Formation of oxomalondiamides
โœ Harry H Wasserman; Kieseung Lee; Mingde Xia ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 166 KB

Oxomalondiamides and related systems are readily formed from derivatives of oxalic acid monoamides. The monoamides are converted to labile triacyl nitriles through cyano ylide intermediates for further coupling with amines and other nucleophiles.

The chemistry of vicinal tricarbonyls a
The chemistry of vicinal tricarbonyls a total synthesis of prodigiosin
โœ Harry H. Wasserman; Louis J. Lombardo ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

The addition of primary amines to alkenyl vicinal tricarbonyls leads to Ssubstituted-3-hydroxypyrroles. This reaction has been employed in a synthesis of the 2formyl-3-methoxy-a,a'-bipyrrole precursor of the prodigiosin family of natural products.