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The chemistry of vicinal tricarbonyls. an efficient synthesis of (±)-vasicine

✍ Scribed by Harry H. Wasserman; Gee-Hong Kuo

Book ID
103402634
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
128 KB
Volume
32
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES

The chemistry of vicinal tricarbonyls a
The chemistry of vicinal tricarbonyls a total synthesis of prodigiosin
✍ Harry H. Wasserman; Louis J. Lombardo 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 206 KB

The addition of primary amines to alkenyl vicinal tricarbonyls leads to Ssubstituted-3-hydroxypyrroles. This reaction has been employed in a synthesis of the 2formyl-3-methoxy-a,a'-bipyrrole precursor of the prodigiosin family of natural products.

The chemistry of vicinal tricarbonyls. F
The chemistry of vicinal tricarbonyls. Formation of oxomalondiamides
✍ Harry H Wasserman; Kieseung Lee; Mingde Xia 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 166 KB

Oxomalondiamides and related systems are readily formed from derivatives of oxalic acid monoamides. The monoamides are converted to labile triacyl nitriles through cyano ylide intermediates for further coupling with amines and other nucleophiles.