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The chemistry of small-ring compounds. Part 51. Electron-transfer-initiated oxidation of some cyclopropylidene compounds

✍ Scribed by A. Hofland; Th. J. de Boer

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
381 KB
Volume
106
Category
Article
ISSN
0165-0513

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📜 SIMILAR VOLUMES

The chemistry of small ring compounds. P
The chemistry of small ring compounds. Part 43. Synthesis of 1-substituted cyclopropyl sulfides
✍ R. Jorritsma; H. Steinberg; Th. J. de Boer 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 874 KB

## Abstract 1‐Hydroxy‐ and 1‐halocyclopropyl sulfides can be conveniently prepared starting from cyclopropanone. Cyclopropyl sulfides with halogen or a dimethylsulfonium group in the α‐position can be transformed into 1‐substituted cyclopropyl sulfides with a variety of nucleophiles. This means tha

The chemistry of small ring compounds. P
The chemistry of small ring compounds. Part 44. Solvolysis of cyclopropyl sulfides and ethers
✍ R. Jorritsma; H. Steinberg; Th. J. de Boer 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 684 KB

## Abstract 1‐Chlorocyclopropyl methyl ether and the corresponding sulfide are methanolysed without any rupture of the three‐membered ring. The solvolysis of 1‐halocyclopropyl sulfides has been studied kinetically and takes place __via__ an __S__~N~1 mechanism. Methyl substituents in the cyclopropy