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The chemistry of small ring compounds. Part 12 radical type substitution reactions of 2-cyclopropylphenol

✍ Scribed by J.R. van der Vecht; H. Steinberg; Th.J. de Boer

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
181 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

Previously we reported on the oxidation of cyclopropanols 1 by metal ions (1).

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## Abstract 1‐Hydroxy‐ and 1‐halocyclopropyl sulfides can be conveniently prepared starting from cyclopropanone. Cyclopropyl sulfides with halogen or a dimethylsulfonium group in the α‐position can be transformed into 1‐substituted cyclopropyl sulfides with a variety of nucleophiles. This means tha

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Only a few examples of thermal [2+2+2] cycloadditions are reported [2] where a C-C single bond participates as a two-electron component. To our knowledge no reaction is known in which an electron-rich C-C single bond is involved In

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AS part of our interest in cyclopropyl compounds with an exocyclic double bond, we have investigated the quaternary ammonium salt 1, l-(o-hydroxyphenyl)cyclo-propyltrimethylammoniumiodide2 under alkaline conditions, normally favouring Hofmann elimination. Heating of 1 with 3.5 eq. of KOH for 36 hrs