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The chemistry of small ring compounds. Part 33 reaction of cyclopropanone acetals with tetracyanoethylene

✍ Scribed by A.A.P. Noordstrand; H. Steinberg; Th.J. de Boer


Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
112 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis


Only a few examples of thermal [2+2+2] cycloadditions are reported [2] where a C-C single bond participates as a two-electron component. To our knowledge no reaction is known in which an electron-rich C-C single bond is involved In


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The chemistry of small ring compounds. P
✍ R. Jorritsma; H. Steinberg; Th. J. de Boer πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 874 KB

## Abstract 1‐Hydroxy‐ and 1‐halocyclopropyl sulfides can be conveniently prepared starting from cyclopropanone. Cyclopropyl sulfides with halogen or a dimethylsulfonium group in the α‐position can be transformed into 1‐substituted cyclopropyl sulfides with a variety of nucleophiles. This means tha