The chemistry of small ring compounds. Part 33 reaction of cyclopropanone acetals with tetracyanoethylene
β Scribed by A.A.P. Noordstrand; H. Steinberg; Th.J. de Boer
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 112 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Only a few examples of thermal [2+2+2] cycloadditions are reported [2] where a C-C single bond participates as a two-electron component. To our knowledge no reaction is known in which an electron-rich C-C single bond is involved In
π SIMILAR VOLUMES
Previously we reported on the oxidation of cyclopropanols 1 by metal ions (1).
## Abstract 1βHydroxyβ and 1βhalocyclopropyl sulfides can be conveniently prepared starting from cyclopropanone. Cyclopropyl sulfides with halogen or a dimethylsulfonium group in the Ξ±βposition can be transformed into 1βsubstituted cyclopropyl sulfides with a variety of nucleophiles. This means tha