The Chemistry of Amine−Azide Interconversion: Catalytic Diazotransfer and Regioselective Azide Reduction
✍ Scribed by Nyffeler, Paul T.; Liang, Chang-Hsing; Koeller, Kathryn M.; Wong, Chi-Huey
- Book ID
- 115493255
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 116 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Chlorotrimethylsilane -sodium iodide reagent (in situ generation of iodotrimethylsilane)in acetonitrile reduces alkyl and aryl/aroyl azides to the corresponding amines/amides in excellent yields under neutral and mild conditions.
A Mild and Facile Reduction of Azides to Amines by N,N-Dimethylhydrazine and Catalytic Ferric Chloride. -A new and convenient method for the reduction of aryl and alkyl azides to the corresponding amines using N,N-dimethylhydrazine in the presence of catalytic amounts of FeCl 3 is described. This r