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Iodotrimethylsilane: A mild and efficient reagent for the reduction of azides to amines

โœ Scribed by Ahmed Kamal; N. Venugopal Rao; E. Laxman

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
161 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Chlorotrimethylsilane -sodium iodide reagent (in situ generation of iodotrimethylsilane)in acetonitrile reduces alkyl and aryl/aroyl azides to the corresponding amines/amides in excellent yields under neutral and mild conditions.

๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: Iodotrimethylsilane
ChemInform Abstract: Iodotrimethylsilane: A Mild and Efficient Reagent for the Reduction of Azides to Amines.
โœ A. KAMAL; N. V. RAO; E. LAXMAN ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 2 views

Iodotrimethylsilane: A Mild and Efficient Reagent for the Reduction of Azides to Amines. -An efficient and chemoselective protocol for the reduction of azides using in situ prepared iodotrimethylsilane as a reducing agent is reported. The corresponding amines are formed in excellent yields. -

Mild and efficient reduction of azides t
Mild and efficient reduction of azides to amines: synthesis of fused [2,1-b]quinazolinones
โœ Ahmed Kamal; K.Venkata Ramana; Hari Babu Ankati; A.Venkata Ramana ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 67 KB

FeCl 3 /NaI has been employed for an efficient reduction of a variety of azides. This method is selective in the presence of a nitro functionality and has been extended for the synthesis of fused [2,1-b]quinazolinone ring systems such as deoxyvasicinone.