The chemical shift anisotropy of 205Tl in a covalent bonding environment
โ Scribed by J.F Hinton; K.R Metz
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 217 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0022-2364
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๐ SIMILAR VOLUMES
The anisotropy of the chemical shift tensor in solid fluorine has been measured by several independent methods to he (1050\*50} x 10-6. This value is slightl,v smaller than the estimated paramagcetic part of the chemical shift from the spin-rotation constant in the gaseous state.
We report on the 2ยฐ5T1 NMR (nuclear magnetic resonance) spectra of the title compounds below and above the superconducting transition temperature Tยข. The TIO layer NMR spectra are dominated by chemical shifts corresponding to TI 3+ with a smaller additional positive Knight shift, whereas a "defect l