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The T1 of the 205Tl+ ion in DMSO: A case of the importance of chemical shift anisotropy

โœ Scribed by J.F Hinton; K.H Ladner


Publisher
Elsevier Science
Year
1978
Weight
248 KB
Volume
32
Category
Article
ISSN
0022-2364

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Anisotropy of the chemical shift tensor
โœ D.E. O'Reilly; E.M. Peterson; Z.M. El Saffar; C.E. Scheie ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 248 KB

The anisotropy of the chemical shift tensor in solid fluorine has been measured by several independent methods to he (1050\*50} x 10-6. This value is slightl,v smaller than the estimated paramagcetic part of the chemical shift from the spin-rotation constant in the gaseous state.