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The cavity elongation effect. Calorimetric studies of the complexes of long-chain carboxylic acids with methyl-α-cyclodextrin in aqueous solutions

✍ Scribed by Giuseppina Castronuovo; Marcella Niccoli


Publisher
Springer Netherlands
Year
2006
Tongue
English
Weight
221 KB
Volume
58
Category
Article
ISSN
0923-0750

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The interaction in water of cyclomaltohexaose (a-cyclodextrin) with monocarboxylic acids from C 3 to C12 has been studied calorimetrically at 25 °C in phosphate buffer, pH 11.3. When a complex forms, calorimetry enables the calculation of both the enthalpy and the association constant, from which th

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The interaction in water of a-and /3-cyclodextrins with L-phenylalanine, L-tyrosine, L-tryptophan, and L-histidine has been studied calorimetrically at 25°C in pure water and in a phosphate buffer (pH 11.3). The interaction in water of a-cyclodextrin with some a, to-amino acids was also studied. Whe