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The Catalyzed Reaction of Alkylmagnesium Halides wth Alkyl Halides. III. 1 Course of the Reaction

✍ Scribed by Parker, V. D.; Noller, C. R.

Book ID: 127240232
Publisher: American Chemical Society
Year: 1964
Tongue: English
Weight: 702 KB
Volume: 86
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01060a031

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When cuprous bromide reacts with an excess of ethylmagnesium bromide in ethyl or c-butyl ether, a copper-containing red solution is formed that markedly catalyzes the reaction of ethyl bromide with ethylmagnesium bromide to give a mixture of ethane and ethylene, 2 usually in the ratio of 1.3 or less

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✍ McDonald, H. J.; Rothstein, L. R.; Robison, H. E. 📂 Article 📅 1944 🏛 American Chemical Society 🌐 English ⚖ 148 KB