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the Catalyzed Reaction of Alkyllmagnesium Halides with Alkyl Halides. II. 1 The Nature of the Catalyst

โœ Scribed by Parker, V. D.; Piette, L. H.; Salinger, R. M.; Noller, C. R.


Book ID
121434971
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
460 KB
Volume
86
Category
Article
ISSN
0002-7863

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Sodium and other inorganic trans-hyponitrites afford tert-alkyl hyponitritea in good yield from the corresponding alkyl bromide or chloride in the presence of weak Lewis acids. Tertiary alkyl hyponitrites have been widely used to initiate free-radical chains in autooxidation and polymerization react