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The catalytic reduction of hydrazine to ammonia by the MoFe3S4 cubanes and implications regarding the function of nitrogenase. Evidence for direct involvement of the molybdenum atom in substrate reduction

✍ Scribed by Coucouvanis, Dimitri; Mosier, Patrick E.; Demadis, Konstantinos D.; Patton, Stephen; Malinak, Steven M.; Kim, Chang G.; Tyson, Marni A.

Book ID: 127168431
Publisher: American Chemical Society
Year: 1993
Tongue: English
Weight: 863 KB
Volume: 115
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00078a079

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A functional model for nitrogenase is currently sought in our laboratory in reactivity studies using various single cubane clusters that possess the [ MFe3S4]" + core, (M = Mo, n = 3; M = V, n = 2). These clusters are used as catalysts for the reduction of enzymatically relevant substrates. Substrat