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Catalytic Reduction of cis -Dimethyldiazene by the [MoFe 3 S 4 ] 3+ Clusters. The Four-Electron Reduction of a NN Bond by a Nitrogenase-Relevant Cluster and Implications for the Function of Nitrogenase

✍ Scribed by Malinak, Steven M.; Simeonov, Anton M.; Mosier, Patrick E.; McKenna, Charles E.; Coucouvanis, Dimitri


Book ID
127377721
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
176 KB
Volume
119
Category
Article
ISSN
0002-7863

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Catalytic and stoichiometric multielectr
✍ Dimitri Coucouvanis; Konstantinos D. Demadis; Steven M. Malinak; Patrick E. Mosi πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 962 KB

A functional model for nitrogenase is currently sought in our laboratory in reactivity studies using various single cubane clusters that possess the [ MFe3S4]" + core, (M = Mo, n = 3; M = V, n = 2). These clusters are used as catalysts for the reduction of enzymatically relevant substrates. Substrat