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Catalytic Reduction of Hydrazine to Ammonia with MoFe 3 S 4 −Polycarboxylate Clusters. Possible Relevance Regarding the Function of the Molybdenum-Coordinated Homocitrate in Nitrogenase

✍ Scribed by Demadis, Konstantinos D.; Malinak, Steven M.; Coucouvanis, Dimitri


Book ID
125421496
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
327 KB
Volume
35
Category
Article
ISSN
0020-1669

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Catalytic and stoichiometric multielectr
✍ Dimitri Coucouvanis; Konstantinos D. Demadis; Steven M. Malinak; Patrick E. Mosi 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 962 KB

A functional model for nitrogenase is currently sought in our laboratory in reactivity studies using various single cubane clusters that possess the [ MFe3S4]" + core, (M = Mo, n = 3; M = V, n = 2). These clusters are used as catalysts for the reduction of enzymatically relevant substrates. Substrat