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The carbon kinetic isotope effects of ozone-alkene reactions in the gas-phase and the impact of ozone reactions on the stable carbon isotope ratios of alkenes in the atmosphere

✍ Scribed by Iannone, R.


Book ID
119660078
Publisher
American Geophysical Union
Year
2003
Tongue
English
Weight
161 KB
Volume
30
Category
Article
ISSN
1944-8007

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The rate law -d[O,]/dt = kl[A][OJ + k3[A][03]2/(k4 + kb[02]) has been found to obrain for the reaction of ozone with allene and with 1,2-butadiene. We now find that this rate law also applies to the reaction of ozone with ethylene and presumably with all lower alkenes. This generalizes the inhibiti