The Cage Effect in Solution and Gas Phase with Application to the Determination of Rate Constants
โ Scribed by Lyon, Richard K.
- Book ID
- 121473122
- Publisher
- American Chemical Society
- Year
- 1964
- Tongue
- English
- Weight
- 636 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Gas-phase rate constants for the reaction of NOz with 16 conjugated olefins were determined a t room temperature by either conventional methods for bimolecular processes or by competitive reactions. It was found that the rate constants for conjugated olefins were larger than those for simple mono-ol
The gas-phase reaction of ozone with C5 -Clo alkenes (eight 1-alkenes, four 1,l-disubstituted alkenes, and cyclohexene) has been investigated a t atmospheric pressure and ambient temperature (285-293 K). Cyclohexane was added to scavenge the hydroxyl radical, which forms as a product of the ozonealk
The gas-phase reaction of ozone with a series of unsaturated oxygenates and with 1-pentene has been studied at ambient T (287-296 K) and atm. of air. Reaction rate p ฯญ 1 constants, in units of cm 3 molecule ฯช1 s ฯช1 , are for 2 (5H)-furanone, ฯช18 10 0.22 ฯฎ 0.05 for methacrolein, for crotonaldehyde, f
The gas-phase decomposition of n-heptyl-1 and n-heptyl-2 hydroperoxides C ~H I ~O O H , which split into two radicals C7H15O and OH, has been investigated in the temperature range of 250-360ยฐC. The decomposition has been carried out in a hydrogen-oxygen mixture (the hydroperoxide represents about 50