๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Rate constants for the reactions of conjugated olefins with NO2 in the gas phase

โœ Scribed by Tomohiro Ohta; Hiroaki Nagura; Shin Suzuki

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
453 KB
Volume
18
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

โœฆ Synopsis

Gas-phase rate constants for the reaction of NOz with 16 conjugated olefins were determined a t room temperature by either conventional methods for bimolecular processes or by competitive reactions. It was found that the rate constants for conjugated olefins were larger than those for simple mono-olefins by factors of 103-104. Temperature dependence studies reveal that the difference in the rate constants for the two types of reactions can primarily be attributed to differences in their activation energies: kl,l.cyclohexad,ene = 5.8 x exp[ -(6.1 2 1 . 6 ) / R T ] cm3 molecule-' s-'; kc,s.2.butene = 4.68 x exp(-ll.P/RT) cm3 molecule-' s-l [23. A linear free energy relationship between the reactions of OH and NO2 with conjugated diolefins was observed.

๐Ÿ“œ SIMILAR VOLUMES

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reaction of ozone with unsaturated oxygenates
โœ Eric Grosjean; Daniel Grosjean ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 160 KB ๐Ÿ‘ 2 views

The gas-phase reaction of ozone with a series of unsaturated oxygenates and with 1-pentene has been studied at ambient T (287-296 K) and atm. of air. Reaction rate p ฯญ 1 constants, in units of cm 3 molecule ฯช1 s ฯช1 , are for 2 (5H)-furanone, ฯช18 10 0.22 ฯฎ 0.05 for methacrolein, for crotonaldehyde, f

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reactions of Ozone with unsaturated Aliphatic Alcohols
โœ Eric Grosjean; Daniel Grosjean ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 431 KB ๐Ÿ‘ 1 views

The gas-phase reaction of ozone with unsaturated alcohols in air has been investigated a t atmospheric pressure and ambient temperature (288-291 K). Cyclohexane was added to scavenge the hydroxyl radical which forms as a product of the ozone-unsaturated alcohol reaction. The reaction rate constants,

Rate coefficients for the gas-phase reac
Rate coefficients for the gas-phase reaction of isoprene with NO3 and NO2
โœ Jeanette R. Stabel; Matthew S. Johnson; Sarka Langer ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 207 KB ๐Ÿ‘ 2 views

## Abstract Rate coefficients for the gasโ€phase reaction of isoprene with nitrate radicals and with nitrogen dioxide were determined. A Teflon collapsible chamber with solid phase micro extraction (SPME) for sampling and gas chromatography with flame ionization detection (GC/FID) and a glass reacto

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reactions of selected dibasic esters with the OH radical
โœ Sara M. Aschmann; Roger Atkinson ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 112 KB ๐Ÿ‘ 2 views

Using a relative rate method, rate constants have been measured for the gasphase reactions of the OH radical with the dibasic esters dimethyl succinate The rate constants ob-298 ฯฎ 3 K. tained were (in units of ): dimethyl succinate, dimethyl 10 cm molecule s 1.4 ฯฎ 0.6; glutarate, and dimethyl adip

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reactions of chlorine atoms with a series of ketones
โœ A. Notario; A. Mellouki; G. Le Bras ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 77 KB ๐Ÿ‘ 2 views

The pulsed laser photolysis-resonance fluorescence technique has been used to determine the absolute rate coefficient for the Cl atom reaction with a series of ketones, at room temperature (298 ฯฎ 2) K and in the pressure range 15-60 Torr. The rate coefficients obtained (in units of cm 3 molecule ฯช1