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The Boron-Mediated Ketone—Ketone Aldol Reaction.

✍ Scribed by Katie M. Cergol; Peter Turner; Mark J. Coster

Publisher
John Wiley and Sons
Year
2005
Weight
31 KB
Volume
36
Category
Article
ISSN
0931-7597

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Remote, 1,5-anti Stereoinduction in the Boron-Mediated Aldol Reactions of β-Oxygenated Methyl Ketones. -The title reaction is investigated with different kinds of aldehydes leading to the desired aldol products with a high level of substrate-based 1,5-stereocontrol. The products are suitable syntho