ChemInform Abstract: Remote, 1,5-anti Stereoinduction in the Boron-Mediated Aldol Reactions of β-Oxygenated Methyl Ketones.

✍ Scribed by I. PATERSON; K. R. GIBSON; R. M. OBALLA

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 34 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199712030

✦ Synopsis

Remote, 1,5-anti Stereoinduction in the Boron-Mediated Aldol Reactions of β-Oxygenated Methyl Ketones.

-The title reaction is investigated with different kinds of aldehydes leading to the desired aldol products with a high level of substrate-based 1,5-stereocontrol. The products are suitable synthons for the construction of polyketides. -(PATERSON, I.;