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ChemInform Abstract: 1,5-Asymmetric Induction in Boron-Mediated Aldol Reactions of β-Alkoxy Methylketones.

✍ Scribed by Luiz C. Dias; Anderson A. de Marchi; Marco A. B. Ferreira; Andrea M. Aguilar

Publisher
John Wiley and Sons
Year
2008
Weight
54 KB
Volume
39
Category
Article
ISSN
0931-7597

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Remote, 1,5-anti Stereoinduction in the Boron-Mediated Aldol Reactions of β-Oxygenated Methyl Ketones. -The title reaction is investigated with different kinds of aldehydes leading to the desired aldol products with a high level of substrate-based 1,5-stereocontrol. The products are suitable syntho