Ab inih SCF MO calculations for the hydrogen-bonded complexes betuxvn niwiles and hydrogen fluoride suggesr a slrong Iintlilr rckuionship between the charge density 01 Ihe hydrogen-bond crilical poinl and the hydrogen-bond energy. Furlher invaligaGon ol the topological properks or the charge density
The bond order—bond length relationship
✍ Scribed by John P. Paolini
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 281 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0192-8651
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A practical procedure for determining the relative strengths of chemical bonds is presented. It is shown, for diatomic and polyatomic molecules, that bond strengths correlate directly with bond orders calculated from force constants and bond lengths. The latter two properties can be obtained either
Rotationally resolved photodissociation spectra of CoKr+ have been observed for an electronic transition in the isolated ion. Analysis yields rotational constants and the angular momentum (spin plus orbit) for both states in the transition. The bond length in vibrationless level of the ground state
The photodissociation spectrum of isolated ZrAr + has been observed. The bond length in the vibrationless ground state is r 0 = 2.718 + 0.01 A with /~" --3/2. The c state of this ion has /2' = 5/2, an electronic origin at Too = 15580 cm-1, a vibrational frequency of to e = 74.9 cm -1, an anharmonici