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The bond length of CoKr+

✍ Scribed by T. Buthelezi; D. Bellert; V. Lewis; P.J. Brucat

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 425 KB
Volume: 242
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00789-7

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✦ Synopsis

Rotationally resolved photodissociation spectra of CoKr+ have been observed for an electronic transition in the isolated ion. Analysis yields rotational constants and the angular momentum (spin plus orbit) for both states in the transition. The bond length in vibrationless level of the ground state of this ion is determined to be r,, = 2.447 & 0.005 A with a rotational structure consistent with a 'A, electronic state. Excited-state diabatic dissociation limits enable the determination of the adiabatic binding energy of ground state of CoKr+ as D,, = 5405 + 1.5 cm-'. These data are discussed in comparison with similar observations in CoAr+ and CoXe+.

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