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The bond length of ZrAr+

✍ Scribed by R.L. Asher; D. Bellert; T. Buthelezi; Dan Lessen; P.J. Brucat

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 292 KB
Volume: 234
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00006-p

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✦ Synopsis

The photodissociation spectrum of isolated ZrAr + has been observed. The bond length in the vibrationless ground state is r 0 = 2.718 + 0.01 A with /~" --3/2. The c state of this ion has /2' = 5/2, an electronic origin at Too = 15580 cm-1, a vibrational frequency of to e = 74.9 cm -1, an anharmonicity of toe x e = 1.15 cm-1, an equilibrium rotational constant of B e = 0.0655, and a rotation-vibration constant of a e = 0.00154 cm-1. The bond length of this excited state is r 0 = 3.050 + 0.01 .A with adiabatic bond energy of 1170 -t-20 cm -1. Assignment of the c-X band convergence places the adiabatic binding energy of ground state of ZrAr + at D o = 2706 + 20 cm -1.

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