The conformation of 2,4-dioxabicyclo[3.3.l]nonane was investigated with the use of lH NMR spectroscopy. From the coupling constants, the Nuclear Overhauser Effects and the T1-relaxation times it was concluded that this compound occurs predominantly in the bc conformation.
The boat-chair conformation of endo-1,5-dimethylbicyclo (3,3,1) nonan-3-ol
β Scribed by W.D.K. Macrosson; J. Martin; W. Parker
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 157 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
We have recently described' rapid reversible 3,7-hydride transfer in the alkoxide of exo-bicyclo[3.3.11 nonan-7-ol-3-one (1). We now report the base-induced rearrangement of the title compound (3) to anti-7,7-dimethylbicycl0[3.3.l]nonan-9-ol-3-one (4) , a process involving 3,9-hydride transfer withi
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Recent developments have made homoadamantsne derivatives readily accessible 1-3 . Cleavage of these compounds would seem a convenient route to 3a,7a\_disubstituted bicyclo[3.3.l]nonsnes. As