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The base-induced rearrangement of endo-7,7-dimethylbicyclo[3.3.1]nonan-3-ol-9-one

✍ Scribed by I. Watt

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
207 KB
Volume
19
Category
Article
ISSN
0040-4039

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✦ Synopsis

We have recently described' rapid reversible 3,7-hydride transfer in the alkoxide of exo-bicyclo[3.3.11 nonan-7-ol-3-one (1). We now report the base-induced rearrangement of the title compound (3) to anti-7,7-dimethylbicycl0[3.3.l]nonan-9-ol-3-one (4) , a process involving 3,9-hydride transfer within the same molecular framework.

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