𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and (non-chair) conformation of some 3α,7α-disubstituted bicyclo[3.3.1.]nonanes

✍ Scribed by J.A. Peters; J.D. Remijnse; A. van der Wiele; H. van Bekkum


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
201 KB
Volume
12
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


Recent developments have made homoadamantsne derivatives readily accessible 1-3 . Cleavage of these compounds would seem a convenient route to 3a,7a_disubstituted bicyclo[3.3.l]nonsnes. As


📜 SIMILAR VOLUMES


Synthesis and Stereochemistry of 7,9-Dis
✍ Nemes, Peter ;Janke, Frank ;Scheiber, Pál 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 406 KB

## Abstract The azabicyclic __endo__ compound 3 was synthesized by reaction of enamine 1 with 2‐benzoyl‐1,3‐dichloropropane (2). The thermodynamically more stable __exo__ isomer 4 was obtained by epimerization of 3 with sodium methoxide. The reduction of 3 and 4 was carried out with different reduc