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The biosynthesis of tigliane and related diterpenoids; an intriguing problem

✍ Scribed by RICHARD J. SCHMIDT

Book ID
114697864
Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
538 KB
Volume
94
Category
Article
ISSN
0024-4074

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An IMDA Approach to Tigliane and Daphnane Diterpenoids: Generation of the Tetracyclic Ring System of the Tiglianes. -The tetracyclic compound (V) representing the ring system of phorbol and other tigliane diterpenes is prepared using an unusual intramolecular Diels-Alder reaction of (I) followed by