A novel chiral synthetic equivalent of dimethyl acetylenedicarboxylate, dimethyl (R)S-2-(10-isobornylsulfinyl)maleate (3), was synthesized. Diels-Alder reaction of (3) with cyclopentadiene proceeded with high stereoand diastereo-selectivity to afford the cycloadduct (4) almost exclusively, which has
β¦ LIBER β¦
The biosynthesis of aristeromycin. Conversion of neplanocin A to aristeromycin by a novel enzymatic reduction
β Scribed by Ronald J. Parry; Yijia Jiang
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 335 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
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