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The axial/equatorial preference of the diphenylphosphino group bonded to the phosphorus of a 2-oxo-1,3,2-dioxaphosphorinanyl ring

✍ Scribed by Andrzej Okruszek; Wojciech J. Stec; Robin K. Harris

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
210 KB
Volume
9
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Proton, ^13^C and ^31^P n.m.r. spectra of the diastereoisomeric 2‐diphenylphosphino‐2‐oxo‐4‐methyl‐1,3,2‐dioxaphosphorinans indicate that the diphenylphosphino group is essentially axial for the trans isomer, whereas it is predominantly equatorial in the case of the cis isomer.

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