Derivatives of 2-Amino-2'-diphenylphosphino-1,1'-binaphthyl (MAP) and Their Application in Asymmetric Palladium(0)-Catalyzed Allylic Substitution. -The novel chiral biaryls (I), readily synthesized from the corresponding N-unsubstituted optically active precursor, are utilized as chiral ligands in
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ChemInform Abstract: Preparation of Enantiomerically Pure 2′-Substituted 2-Diphenylphosphino-1,1′-binaphthyls by Reductive Cleavage of the Carbon—Phosphorus Bond in a Borane Complex of 2-Diphenylphosphino-2′-diphenylphosphinyl-1,1′-binaphthyl.
✍ Scribed by Toyoshi Shimada; Hiroaki Kurushima; Yong-Hwan Cho; Tamio Hayashi
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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