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An Original Approach to the Synthesis of Phosphorus—Carbon Heterocycles — The 3-Oxo-2,3-dihydro-1,3-oxaphospholes.

✍ Scribed by David Virieux; Ciptadi Ciptadi; Yves-Alain Bekro; Henri-Jean Cristau


Publisher
John Wiley and Sons
Year
2004
Weight
16 KB
Volume
35
Category
Article
ISSN
0931-7597

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An Original Approach to the Synthesis of
✍ David Virieux; Ciptadi Ciptadi; Yves-Alain Bekro; Henri-Jean Cristau 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 167 KB

## Abstract The synthesis of new highly functionalized phosphorus heterocycles, the 3‐oxo‐2,3‐dihydro‐1,3‐oxaphospholes, was achieved by a cyclization reaction involving malonic enolates as 1,3‐__O__,__C__‐dinucleophiles and phosphorus compounds, such as (chloromethyl)phosphinic chlorides or alkyl