The analysis of solvent effects on the kinetics of simple heterogeneous electron transfer reactions
β Scribed by W.Ronald Fawcett; Colby A. Foss Jr.
- Book ID
- 107793241
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 561 KB
- Volume
- 252
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
## Abstrae~lvent effects studied in simple heterogeneous redox reactions, and for amalgam formation reactions have been reviewed. It is emphasized that on the basis of a regression analysis of the data, solvent effects relating to the pm-exponential factor of the electron transfer rate wnstant can
## Solvent effects in simple electron transfer reactions are reviewed. It is shown that estimation of the outer sphere Gibbs activation energy is often difficult. Data for the electroreduction of Fe(H20):+ at single crystal gold electrodes are also discussed. This system shows a very large double