The .alpha. effect: on the origin of transition-state stabilization
β Scribed by Hoz, Shmaryahu
- Book ID
- 127291710
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 434 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The quazitative HOMO-LVMO orbital interaction interpretation of the aZpha effect is found to be invaZid for anionic nucleophiles. In any event, gas phase SN2 reactions of HOO-and FO'O-show no evidence of the effect. The role of a hydroxylic solvent requires greater consideration as the source of pos
Richard S. Herrick' and paul J. Botelho Department of Chemistry. College of the Holy Cross, Worcester, Massachusetts, 01610 Received October 12, 1991; accepted January 22, 1992 Equilibrium constants between \(3.9(1.2) \times 10^{3}\) and \(7.3(1.7) \times 10^{4} \mathrm{M}^{-1}\) are reported for