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Aromatic transition states and the .alpha. effect

โœ Scribed by Liebman, Joel F.; Pollack, Ralph M.


Book ID
126884076
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
285 KB
Volume
38
Category
Article
ISSN
0022-3263

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The quazitative HOMO-LVMO orbital interaction interpretation of the aZpha effect is found to be invaZid for anionic nucleophiles. In any event, gas phase SN2 reactions of HOO-and FO'O-show no evidence of the effect. The role of a hydroxylic solvent requires greater consideration as the source of pos