๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Theoretical studies of SN2 transition states, the alpha effect

โœ Scribed by Saul Wolfe; D.J. Mitchell; H. Bernhard Schlegel; C. Minot; O. Eisenstein

Book ID
104220404
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
301 KB
Volume
23
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The quazitative HOMO-LVMO orbital interaction interpretation of the aZpha effect is found to be invaZid for anionic nucleophiles. In any event, gas phase SN2 reactions of HOO-and FO'O-show no evidence of the effect. The role of a hydroxylic solvent requires greater consideration as the source of positive deviations from rate-equiZibrim plots.

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