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The alkylation of some ruthenium(II) complexes of ambident heterocyclic ligands

✍ Scribed by Edwin C. Constable; Jack Lewis


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
342 KB
Volume
254
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES


Bis(acetylido) Complexes of Ruthenium(II
✍ Leslie D. Field; Alison M. Magill; Scott J. Dalgarno; Paul Jensen πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 378 KB

## Abstract Terminal acetylenes react with __cis__‐RuMe~2~(PMe~3~)~4~ to form the bis(acetylido) complexes __cis__/__trans__‐Ru(C≑CR)~2~(PMe~3~)~4~ in good yield. The structures of __trans__‐2 (R = Ph), __cis__‐3 (R = __p__‐C~6~H~4~‐OMe), __trans__‐4 (R = __p__‐C~6~H~4~‐Me), __cis__‐6 (R = Me), __t

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The temperature dependence of photosubstihrtion for several polypyridine ruthenium@) complexes has been examined. In contrast to the parent tris-bipyridineruthenium(lI), little temperature dependence is observed. These results. combined with quenchmg data, provide kinetic details on the intermediate