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Photoinduced Ligand Isomerization in Dimethyl Sulfoxide Complexes of Ruthenium(II)

✍ Scribed by Matthew K. Smith; John A. Gibson; Charles G. Young; John A. Broomhead; Peter C. Junk; F. Richard Keene


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
365 KB
Volume
2000
Category
Article
ISSN
1434-1948

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Dynamics of ligand field excited states
✍ Leslie J. Henderson; William R. Cherry 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 307 KB

The temperature dependence of photosubstihrtion for several polypyridine ruthenium@) complexes has been examined. In contrast to the parent tris-bipyridineruthenium(lI), little temperature dependence is observed. These results. combined with quenchmg data, provide kinetic details on the intermediate