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The alkyl group effect in the alkylations of ethyl acetoacetate in dimethyl sulfoxide

✍ Scribed by W.J. le Noble; J.E. Puerta

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
164 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis

Recent insights (1) in the remarkable solvent properties of dimethyl eulfoxida (DMSO), and our own interest in the chemistry of isopropcnyl ethers (2) led u8 to consider the poraibility of direot 0-alkylation of ethyl aoetoaoetate in that solvent. The connection i# that Kornblum'rr work (3) suggests increaasd &alkylat.ion of ambidmt anions when the oxygen atcrP is strongly solvated, and that cations mther

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