The aldol reaction of lithiopinacolonate with substituted benzaldehydes. Solvent and structure effects on aggregation, electrochemistry, and heat of reaction
✍ Scribed by Arnett, Edward M.; Palmer, Carrie A.
- Book ID
- 127350850
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 922 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
The E/Z ratios of the stilbenes 1 formed in the Wittig reaction of ortho-halo substituted benzyltriphenylphosphonium salts 2 and benzaldehydes 3 were determined. It was found that there is a co-operative effect of one ortho-halo group on each of the two reacting partners which increases Z-selectivit
## Abstract The rate constants for the reaction of 2‐methyl‐cyclohex‐1‐enylcarboxylic, 2‐phenylcyclohex‐1‐enylcarboxylic, and 2‐methylbenzoic and 2‐phenylbenzoic acids with diazodiphenyl‐methane were determined in 14 various solvents at 30°C. To explain the kinetic results through solvent effects,