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Solvent and substituent effects on the redox reactions of para-substituted tetraphenylporphyrin

✍ Scribed by Kadish, Karl M.; Morrison, Mark M.

Book ID
121382062
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
344 KB
Volume
98
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Substituent effects on the redox reactio
Substituent effects on the redox reactions of tetraphenylporphyrins
✍ Karl M Kadish; Mark M Morrison πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science βš– 543 KB

The effect of substituents on pi radical reactions of para-substituted tetraphenylporphyrins was investigated by cyclic voltammetry in methylene chloride. In all cases electron donating substituents produced a more difficult reduction and an easier oxidation. Plots of E1/2 vs. a yielded Hammett line

Solvent and substituent effects on the e
Solvent and substituent effects on the electrochemical oxidation of para- and meta-substituted anilines
✍ D. S. Bhuvaneshwari; K. P. Elango πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 293 KB πŸ‘ 2 views

## Abstract Electrochemical oxidation of 15 para‐ and meta‐substituted anilines in different mole fractions of water in 2‐methylpropan‐2‐ol has been investigated in the presence of 0.1 M sulfuric acid as a supporting electrolyte. The oxidation potential data of anilines correlate well with the Brow