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Substituent effects on the redox reactions of para-substituted tetraphenylporphyrin complexes of ruthenium(II)

โœ Scribed by Malinski, T.; Chang, D.; Bottomley, L. A.; Kadish, K. M.


Book ID
119945776
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
763 KB
Volume
21
Category
Article
ISSN
0020-1669

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Substituent effects on the redox reactio
โœ Karl M Kadish; Mark M Morrison ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science โš– 543 KB

The effect of substituents on pi radical reactions of para-substituted tetraphenylporphyrins was investigated by cyclic voltammetry in methylene chloride. In all cases electron donating substituents produced a more difficult reduction and an easier oxidation. Plots of E1/2 vs. a yielded Hammett line