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A study of solvent and substituent effects on the redox potentials and electron-transfer rate constants of substituted iron meso-tetraphenylporphyrins

โœ Scribed by Kadish, K. M.; Morrison, M. M.; Constant, L. A.; Dickens, L.; Davis, D. G.


Book ID
121400382
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
492 KB
Volume
98
Category
Article
ISSN
0002-7863

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Substituent effect on the redox potentia
โœ Wu Guo-Zhang; Leung (Xiaoguang Liang) Hiu-Kwong; Gan Wei-Xing ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 639 KB

meso-Substituent effect on the redox properties of octaethylporphyrin and its zinc(lI) and copper(I1) complexes are investigated with cyclic volatmmetry. The El/2 values were observed to correlate linearly with Hammett's d, constant for the first and second oxidation reaction and the first reduction