The additional activation volume of unimolecular reactions in the solid phase
โ Scribed by G. B. Manelis; G. M. Nazin; V. G. Prokudin
- Book ID
- 110160468
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2006
- Tongue
- English
- Weight
- 139 KB
- Volume
- 411
- Category
- Article
- ISSN
- 0012-5016
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๐ SIMILAR VOLUMES
Trajectory studies on a model for the isomerisation of CHSNC to CH,CN show that rotational energy suppresses the rate of isomerisation. This is in contrast to the effect of rotation on a dissociation reaction. The effect is due to the generation of a centrifugal barrier along the reaction coordinate
## Abstract The kinetics of the gasโphase elimination of benzaldoxime was determined in a static reaction system over the temperature and pressure range 350ยฐCโ400ยฐC and 56โ140 Torr, respectively. The products obtained were benzonitrile and water. The reaction was found to be homogeneous, unimolecul